We studied Betta fish and their aggressive behavior in reaction to a perceived threat stimulus at two different distances. Betta fish have been known to display aggressive behaviors when in the presence of other fish and at their own reflection. We hypothesize that the Betta fish will display more aggressive behaviors when a mirror is present and at a closer proximity because a close mirror may replicate the experience of a more immediate threat. To test this, we placed mirrors at one or eight inches away from their tanks and observed. If the Bettas flared their fins and rubbed their faces against the side of the tank, we characterized their behavior as aggressive. We found that our hypothesis was incorrect and there was no signficant difference between aggression presentation at one or eight inches. Additionally, we compared aggressive behavior in Delta Tail Bettas and Veiltail Bettas. We hypothesized that there would be a difference in aggression between the two betta species. Our hypothesis was supported, and we found that Delta Tail Bettas were significantly more aggressive than Veiltail Bettas. For breeders and owners of novelty fish, knowing what stimlui results in aggressive behavior can be beneficial for preventing stress and choosing what species to breed and own. Furthermore, studies on aggression in bettas allows researchers to study how aggression relates to survival and mating, and how bettas compared to related species.

Crows are social creatures meaning that they communicate within groups valuable and pertinent information. This information can relay to others where food might be and where there might be a predator. Not only do they have this attribute, but more importantly, they can also retain this knowledge over a period of time. For our experiment, we wanted to test whether American Crows, Corvus Brachyrhynchos, had the same ability as chickadees to encode and differentiate different types of conspecific calls. We compared the difference in time of each crow vocalization between a food call and a mobbing call. After running a t-test, we found that our experiment yielded significant results. This implies that crows, similar to chickadees can distinguish and respond to calls differently depending on the type of call. This gives us insight on possible crow behaviors and explanations and a basis for future crow research.

Protons take part in many important reactions such as redox, acid-base chemistry and biochemistry; however, the mechanisms for proton transfer and hydronium’s stabilization are less understood. Hydronium sequestered in 18-crown-6 ether (CE) has an unusually broad and intense vibrational absorbance (OH-feature) compared to bare hydronium. One environmental factor affecting this OH-feature is the range of hydrogen bonded geometries between the hydrogen atoms in hydronium and the oxygen atoms in the CE, which is sampled by the complex even in its ground vibrational state. The breadth of the OH-feature is attributed to changes of the OH stretch frequency of hydronium as it rattles within the CE, and to the CE distorting to accommodate the hydronium. Hydronium will donate a proton to diethyl ether in the binary complex, because the diethyl ether is a stronger base than water. However, when hydronium hydrogen bonds to three diethyl ether molecules in a ternary complex, all three hydrogen atoms in hydronium are pulled by the ether molecules preventing any one of the protons from transferring. The hydrogen bonded geometries we analyze involve complexes of hydronium with both simple ethers and cyclic CE molecules. The CE hydrogen bonds to all three of the hydrogen atoms in hydronium similarly to the ternary complex, thus the CE complex prevents proton transfer. We explore several other environmental factors, including increasing the rigidity of the CE by replacing carbon-carbon single bonds with carbon-carbon double bonds. This increase in CE rigidity reduces the rattling of the hydronium. We also explore the effects of reducing electron density on the oxygen atoms in the CE by replacing hydrogen atoms in the CE with fluorine atoms. Optimizations, frequencies and potential energy scans are made at the B3LYP level of theory using a 6-311G(2d,p) basis.